Sulfur-Sulfur Bond Cleavage Processes. Selective Desulfurization of Trisulfides

DOI: 10.1021/ja00386a034

Source and publish data:

Journal of the American Chemical Society p. 6045 - 6053 (1982)

Update date:2022-09-26

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Authors:

Harpp, David N.

Smith, Roger A.

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Article abstract of DOI:10.1021/ja00386a034

The selectivity of sulfur removal in the desulfurization of trisulfides by tertiary phosphorus compounds has been investigated in detail.A mechanistic rationalization is proposed to account for central/terminal sulfur extrusion variation as a function of substrate structure and solvent polarity.

Full text of DOI:10.1021/ja00386a034

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