Tetrahedron Letters p. 6839 - 6842 (1988)
Update date:2022-07-29
Topics:
Creary, Xavier
Sky, Anthony F.
Mehrsheikh-Mohammadi, M. E.
The CF3 group, in conjunction with an electron donor group, can enhance the rate of the methylenecyclopropane rearrangement.This is attributed to captodative radical stabilization of the intermediate biradical.
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Doi:10.1021/acs.orglett.9b01105
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(1973)Doi:10.1007/BF00601119
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