Tetracyanoethylene-hydrogen peroxide, a mild epoxidation system of olefins

DOI: 10.1248/cpb.43.686

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 686 - 688 (1995)

Update date:2022-08-05

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Authors:

Masaki Masaki

Miura Miura

Mukai Mukai

Iwata Iwata

Oda Oda

Itoh Itoh

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Article abstract of DOI:10.1248/cpb.43.686

A reagent combination system, tetracyanoethylene-30% hydrogen peroxide, was found to epoxidize olefins efficiently in acetonitrile at room temperature in a stereospecific manner with retention of the configuration of the double bond.

Full text of DOI:10.1248/cpb.43.686

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