Perfluoroalkylations of Carbanions with (Perfluoroalkyl)-phenyliodonium Triflates (FITS Reagents)

Article abstract of DOI:10.1246/bcsj.59.439

FITS reagents reacted with primary alkylmagnesium halides in THF at -78 deg C to give the corresponding perfluoroalkyl(R_f)-alkanes in moderate to good yields.But an alkyl-lithium or -copper gave a poor yield of the R_f-product.The rea