Perfluoroalkylations of Carbanions with (Perfluoroalkyl)-phenyliodonium Triflates (FITS Reagents)

DOI: 10.1246/bcsj.59.439

Source and publish data:

Bulletin of the Chemical Society of Japan p. 439 - 446 (1986)

Update date:2022-07-29

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Authors:

Umemoto, Teruo

Gotoh, Yoshihiko

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Article abstract of DOI:10.1246/bcsj.59.439

FITS reagents reacted with primary alkylmagnesium halides in THF at -78 deg C to give the corresponding perfluoroalkyl(R_f)-alkanes in moderate to good yields.But an alkyl-lithium or -copper gave a poor yield of the R_f-product.The rea

Full text of DOI:10.1246/bcsj.59.439

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