Tetrahedron p. 5969 - 5978 (1993)
Update date:2022-08-03
Topics:
Hashimoto, Yukihiko
Hirata, Kazujuki
Kagoshima, Hirotaka
Kihara, Nobuhiro
Hasegawa, Masaki
Saigo, Kazuhiko
In the presence of gallium dichloride, the reaction of carbonyl compounds or their dimethylacetals with aromatic compounds afforded Friedel-Crafts alkylated adducts in good yields.It was suggested that the adducts were obtained by way of a reduction of the carbonyl compounds or their dimethylacetals, followed by the Friedel-Crafts reaction in one-pot.This is the first organic synthetic method with gallium dichloride, low valent gallium.
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