SYNTHESE D'AZIRIDINES N-NON SUBSTITUTEES PAR REDUCTION DE SELS D'HYDRAZONIUM

Article abstract of DOI:10.1016/S0040-4039(01)81284-3

Z and E N,N,N-trimethylhydrazonium iodides from α,β-unsaturated cyclohexenones are reduced in good yields into saturated aziridines or α,β-unsaturated aziridines by sodium bis (2-methoxy ethoxy) aluminium hydride.Partly hydrolysed hydride leads to reverse proportions of saturated and α,β-unsaturated aziridines.