THE FORMATION OF DIAZOALKANE AND DIAZENIDO-COMPLEXES FROM THE REACTION OF METHYL BROMIDE WITH trans-BISBIS(DINITROGEN)TUNGSTEN IN VARIOUS SOLVENTS

DOI: 10.1039/DT9800001129

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1129 - 1134 (1980)

Update date:2022-08-02

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Authors:

Chatt, Joseph

Head, Robert A.

Leigh, Jeffery G.

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Article abstract of DOI:10.1039/DT9800001129

The reaction of trans- with MeBr in solvents such as tetrahydrofuran, 2-methyltetrahydrofuran, and tetrahydropyran leads to new diazenido-complexes via a route which is now well understood.These new complexes undergo reversible ring opening with protic acids to yield substituted-diazoalkane complexes.N-Methylpyrrolidine and tetrahydrothiophen similarly form diazenido-derivatives, which react with acids to form hydrazido(2-)-compounds and do not undergo ring opening.

Full text of DOI:10.1039/DT9800001129

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