Journal of the Chemical Society, Dalton Transactions p. 1129 - 1134 (1980)
Update date:2022-08-02
Topics:
Chatt, Joseph
Head, Robert A.
Leigh, Jeffery G.
The reaction of trans-a route which is now well understood.These new complexes undergo reversible ring opening with protic acids to yield substituted-diazoalkane complexes.N-Methylpyrrolidine and tetrahydrothiophen similarly form diazenido-derivatives, which react with acids to form hydrazido(2-)-compounds and do not undergo ring opening.
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