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Preparation and Structure of Certain Phosphorus-centred Radical Cations

DOI: 10.1039/f19848001005

Source and publish data:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1005 - 1016 (1984)

Update date:2022-08-03

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Authors:

Hasegawa, AkinoriHasegawa, Akinori

McConnachie, Glen D. G.McConnachie, Glen D. G.

Symons, Martyn C. R.Symons, Martyn C. R.

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Article abstract of DOI:10.1039/f19848001005

Exposure of dilute solutions of various trivalent phosphorus derivatives, PL3, in fluorotrichloromethane to (60)Co γ-rays at 77 K gave the corresponding cations, <.PL3>(1+), characterised by their e.s.r. spectra.The spectra establish that the SOMO for these cations is considerably localised on phosphorus, which contributes extensive atomic 3s and 3p character.The results confirm and extend previous studies using sulphuric acid matrices.The tendency for these cations to react with corresponding neutral molecules to give ?* dimer-cations PL3>(1+) is also confirmed. The structures of these species are discussed and compared with those of related radicals.

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