Journal of Organometallic Chemistry p. 75 - 86 (1994)
Update date:2022-08-02
Topics:
Schenk, Wolfdieter A.
Khadra, Almuetassem
Burschka, Christian
The organotin halides RnSnX4-n (R=Ph, 4-MeC6H4, 4-FC6H4; X=Cl, Br; n=0, 1, 2, 3) and Me2SnCl2 form adducts with thiirane-1-oxide.In general, for n=0, 1, 2 these have a 1:2 stoichiometry and are octahedral, as shown by a single-crystal structural study of <(4-FC6H4)2SnCl2(C2H4SO)2> (4c).In 4c the aryl groups are trans to each other and the chloride and sulphoxide ligands mutually cis.The S-O bond is 0.04 Angstroem longer than that in uncoordinated thiirane-1-oxide, whereas the bonds within the three-membered ring are shortened by a similar amount.Depending on the reaction conditions, 1:1 adducts
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