Journal of the Chemical Society. Chemical communications p. 260 - 261 (1984)
Update date:2022-08-04
Topics: Stereochemistry Mechanism Nickel-catalysed Hydrocyanation Conjugated dienes
Baeckvall, Jan-E.
Andell, Ove S.
Nickel-catalysed addition of deuterium cyanide to cyclohexa-1,3-diene was shown to occur with cis stereochemistry, indicating that a cis-migration of co-ordinated cyanide takes place in an intermediate ?-allylnickel complex.
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