Stereochemistry and Mechanism of the Nickel-catalysed Hydrocyanation of Conjugated Dienes

DOI: 10.1039/C39840000260

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 260 - 261 (1984)

Update date:2022-08-04

Topics: Stereochemistry Mechanism Nickel-catalysed Hydrocyanation Conjugated dienes

Authors:

Baeckvall, Jan-E.

Andell, Ove S.

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Article abstract of DOI:10.1039/C39840000260

Nickel-catalysed addition of deuterium cyanide to cyclohexa-1,3-diene was shown to occur with cis stereochemistry, indicating that a cis-migration of co-ordinated cyanide takes place in an intermediate ?-allylnickel complex.

Full text of DOI:10.1039/C39840000260

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