Journal of Organic Chemistry p. 2874 - 2880 (1980)
Update date:2022-08-05
Topics: Rearrangement Cyclobutanones
Wasserman, Harry H.
Hearn, Michael J.
Cochoy, Robert E.
Vinylcyclopropanols, formed by the addition of vinylmagnesium bromide to the ethyl hemiketal of cyclopropanone, may be converted to cyclobutanone derivatives on reaction with various electrophiles.The ring enlargement of 1-vinyl-2-methylcyclopropanol takes place by preferential migration of the more highly substituted carbon atom.
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