(R)- AND (S)-2-ACETOXY-1,1,2-TRIPHENYLETHANOL - EFFECTIVE SYNTHETIC EQUIVALENTS OF A CHIRAL ACETATE ENOLATE

DOI: 10.1016/S0040-4039(01)91110-4

Source and publish data:

Tetrahedron Letters p. 5031 - 5034 (1984)

Update date:2022-08-04

Topics:

Authors:

Braun, Manfred

Devant, Ralf

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Article abstract of DOI:10.1016/S0040-4039(01)91110-4

The enolate 3, easily available by double deprotonation of (R)-2-acetoxy-1,1,2-triphenylethanol (5), adds in a highly stereoselective manner to aldehides.Hydrolysis of the adducts 6/7 affods the acids 2.

Full text of DOI:10.1016/S0040-4039(01)91110-4

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