Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1533 - 1554 (1983)
Update date:2022-08-05
Topics:
Douglas, Monte A.
Hauge, Robert H.
Margrave, John L.
This paper reports an investigation of the electronic structures of the Group IIIA metal atom hydration reaction intermediates (M<*>OH2 adducts) and their subsequent photolysis products (HMOH, MOH and MO) where M = Al, Ga and In.The metal-water interaction in the adduct is sufficiently strong to perturb the electronic structure of the metal atom; consequently, one observes a unique band structure for the adduct that is red shifted from the metal's atomic resonance transition.Molecular orbital and electronic state-to-state correlations are presented.
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