Diastereoselective Diels-Alder reactions between substituted 1,3-butadienes and N-α-methylbenzylmaleimide

DOI: 10.1016/S0040-4039(00)79415-9

Source and publish data:

Tetrahedron Letters p. 5877 - 5880 (1991)

Update date:2022-08-03

Topics:

Authors:

Baldwin Baldwin

Greenspan

Alaimo Alaimo

McPhail McPhail

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Article abstract of DOI:10.1016/S0040-4039(00)79415-9

The TiCl₄ catalyzed reaction between 2-t-butyl-1,3-butadiene and N-α-methylbenzylmaleimide at -65°C affords diastereomeric Diels-Alder adducts in a 15:1 ratio. The structure of the major adduct was determined by x-ray.

Full text of DOI:10.1016/S0040-4039(00)79415-9

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