Journal of Organometallic Chemistry p. 39 - 52 (1989)
Update date:2022-08-03
Topics: Synthesis Crystal structure Electron density Chlorination NMR (nuclear magnetic resonance) Steric Effects Spectroscopic Analysis Coordination Geometry X-ray Diffraction (XRD) Silyl group Organophosphorus Compound Single-Crystal X-Ray Analysis
Al-Juaid, Salih S.
Dhaher, Saadi M.
Eaborn, Colin
Hitchcock, Peter B.
McGeary, Catherine A.
Smith J. David
The compounds TsiPCl2 (Tsi=(Me3Si)3C) (I), and TpsiPCl2 (Tpsi=<(PhMe2Si)3C> (II), have been obtained by the reaction of TsiLi or TpsiLi with PCl3.In the case of TsiLi the reaction conditions could be varied so that 50 percent yields of the diphosphene Tsi
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