Journal of the Chemical Society. Perkin transactions I p. 3008 - 3011 (1981)
Update date:2022-07-30
Topics:
Cooper, Melanie M.
Hignett, Geoffrey J.
Joule, John A.
The synthesis are described of <2>benzoxepino<4,3-b>indol-11(6H,12H)-one, (12a) and 12-methylpyrido<4',3':3,4>oxepino<3,2-b>indol-5(6H,12H)-one, (5), by sequences involving the first examples of intramolecular nucleophilic substitution at an indole β-position, with departure of phenylsulphinate as leaving group from nitrogen.The spectroscopic and chemical evidence supporting the structures for these new heterocyclic systems, and thus by implication the operation of indole β-nucleophilic substitution, are detailed.
View MoreTaizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
SuZhou Ascepion Pharmaceuticals, Inc.(expird)
Contact:0512-86881668
Address:Building C,68Xingqing Road,Suzhou,China.
LianYunGang Chiral Chemical(CHINA) CO.,LTD
Contact:+86-518-83616958 +86-519-82884848
Address:LianYunGang Chemical Industry Park (JiangSu)
Wuhan Better Organic Technology Inc.
Contact:13307163183
Address:Wuhan Economic&Technology Development Zone, Hubei
Contact:021-50278900
Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Doi:10.1016/j.carres.2009.07.013
(2009)Doi:10.1007/s13738-021-02344-3
(2022)Doi:10.1016/S0040-4039(00)86719-2
(1988)Doi:10.1016/j.bmcl.2006.10.063
(2007)Doi:10.1002/jhet.5570380526
(2001)Doi:10.1055/s-0036-1588070
(2016)
