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Manganese-Catalyzed Silylmagnesiation of Acetylenes and 1,3-Dienes

DOI: 10.1246/bcsj.70.245

Source and publish data:

Bulletin of the Chemical Society of Japan p. 245 - 251 (1997)

Update date:2022-08-05

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Authors:

Tang, JunTang, Jun

Shinokubo, HiroshiShinokubo, Hiroshi

Oshima, KoichiroOshima, Koichiro

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Article abstract of DOI:10.1246/bcsj.70.245

The treatment of 4-benzyloxy-1-butyne with PhMe2SiMgMe in the presence of a catalytic amount of MnCl2 gave a monosilylated product, (E)-PhCH2OCH2CH2CH=CHSiMe2Ph, selectively after an aqueou

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Full text of DOI:10.1246/bcsj.70.245

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