Manganese-Catalyzed Silylmagnesiation of Acetylenes and 1,3-Dienes

DOI: 10.1246/bcsj.70.245

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Bulletin of the Chemical Society of Japan p. 245 - 251 (1997)

Update date:2022-08-05

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Authors:

Tang, Jun

Shinokubo, Hiroshi

Oshima, Koichiro

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Article abstract of DOI:10.1246/bcsj.70.245

The treatment of 4-benzyloxy-1-butyne with PhMe₂SiMgMe in the presence of a catalytic amount of MnCl₂ gave a monosilylated product, (E)-PhCH₂OCH₂CH₂CH=CHSiMe₂Ph, selectively after an aqueou

Full text of DOI:10.1246/bcsj.70.245

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