ETHER CLEAVAGE BY ACTIVATED METALS. I. CLEAVAGE OF TETRAHYDROFURAN BY TRANSITION-METAL ACTIVATED MAGNESIUM

DOI: 10.1016/0022-328X(85)87208-9

Source and publish data:

Journal of Organometallic Chemistry p. 149 - 158 (1985)

Update date:2022-09-26

Topics:: Authors:

Bartmann, Ekkehard

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Article abstract of DOI:10.1016/0022-328X(85)87208-9

Transition metal complexes obtained by reduction of transition metal chlorides with magnesium catalyze a slow insertion reaction of magnesium into carbon-oxygen bonds of tetrahydrofuran and other ethers.The order of reactivity of the transition metals tested is Ti ca.Co > V > Cr > Zr > Rh > Mn > Nb > Fe ca.Ni.The effects on the reaction of modifications of the catalysts are discussed.

Full text of DOI:10.1016/0022-328X(85)87208-9

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Article Doi

ETHER CLEAVAGE BY ACTIVATED METALS. I. CLEAVAGE OF TETRAHYDROFURAN BY TRANSITION-METAL ACTIVATED MAGNESIUM

DOI: 10.1016/0022-328X(85)87208-9

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(85)87208-9

Full text of DOI:10.1016/0022-328X(85)87208-9

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