Journal of Organic Chemistry p. 4901 - 4904 (1990)
Update date:2022-08-04
Topics:
Labroo, Rita B.
Cohen, Louis A.
The diastereomers of dioxindolyl-L-alanine are obtained in a 1:1 ratio by air oxidation of oxindolyl-L-alanine.Preparative separation of the diastereomers is achieved by reverse-phase HPLC.Stereochemistry of the hydroxyl group at C-3 is assigned by transformation to a related pair of diastereomers of known stereochemistry.
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