Journal of the Chemical Society - Faraday Transactions p. 2901 - 2904 (1994)
Update date:2022-08-03
Topics:
Ichikawa, Takahisa
Ohta, Nobuaki
Shiotani, Masaru
Radiolysis of the two systems, pentane containing 3 molpercent octane, and hexane containing 3 molpercent nonane, has been investigated at 77 K in the presence of 1 molpercent alkenes.EPR studies of alk-2- and -3-ene additives show the formation of the corresponding alk-2-and -3-ene radical cations, whereas alk-1-enes with linear C-C chains are observed to give (E)-pent-2-ene radical cations in the pentane systems and (E)-hex-3-ene radical cations in the hexane systems.The effects of the alk-1-ene additives are attributed to the ion-molecule reaction, i.e. transfer of H2 from the parent n-alkane radical cations to the alk-1-ene additives to form the alkene radical cations of the parent molecules.
View MoreHAINAN JINYING IMPORT AND EXPORT CO. LTD
Contact:+86-898-32875423
Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA
Changzhou Anyi Biochem Co., Ltd.(expird)
Contact:+86-519-88836158
Address:no,51 caoda
Contact:+86-731-84427351
Address:154 JIANXIANG SOUTH ROAD
Contact:+86-25-85281586
Address:13F,Bld2#,South of Longpan Road
Contact:+86-577-65618087-605
Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.
Doi:10.1007/BF00480138
()Doi:10.1021/ja01171a071
(1949)Doi:10.1007/BF01046455
(1977)Doi:10.1016/S0008-6215(00)83300-5
(1977)Doi:10.1002/hlca.19770600835
(1977)Doi:10.1016/S0022-1139(00)81521-3
(1982)
