Journal of the Chemical Society - Faraday Transactions p. 2901 - 2904 (1994)
Update date:2022-08-03
Topics:
Ichikawa, Takahisa
Ohta, Nobuaki
Shiotani, Masaru
Radiolysis of the two systems, pentane containing 3 molpercent octane, and hexane containing 3 molpercent nonane, has been investigated at 77 K in the presence of 1 molpercent alkenes.EPR studies of alk-2- and -3-ene additives show the formation of the corresponding alk-2-and -3-ene radical cations, whereas alk-1-enes with linear C-C chains are observed to give (E)-pent-2-ene radical cations in the pentane systems and (E)-hex-3-ene radical cations in the hexane systems.The effects of the alk-1-ene additives are attributed to the ion-molecule reaction, i.e. transfer of H2 from the parent n-alkane radical cations to the alk-1-ene additives to form the alkene radical cations of the parent molecules.
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