Journal of the Chemical Society - Faraday Transactions p. 2901 - 2904 (1994)
Update date:2022-08-03
Topics:
Ichikawa, Takahisa
Ohta, Nobuaki
Shiotani, Masaru
Radiolysis of the two systems, pentane containing 3 molpercent octane, and hexane containing 3 molpercent nonane, has been investigated at 77 K in the presence of 1 molpercent alkenes.EPR studies of alk-2- and -3-ene additives show the formation of the corresponding alk-2-and -3-ene radical cations, whereas alk-1-enes with linear C-C chains are observed to give (E)-pent-2-ene radical cations in the pentane systems and (E)-hex-3-ene radical cations in the hexane systems.The effects of the alk-1-ene additives are attributed to the ion-molecule reaction, i.e. transfer of H2 from the parent n-alkane radical cations to the alk-1-ene additives to form the alkene radical cations of the parent molecules.
View MoreContact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Qingdao XinYongAn Chemicals Co., Ltd
Contact:+86-532-81107967
Address:Chengyang dual-port industrial park by the sea，Qingdao
Contact:+86-10-83993285
Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Shanghai Massive Chemical Technology Co., Ltd.
website:http://www.massivechem.com/
Contact:+86 21 34943721
Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Hunan Shineway Enterprise Co., Ltd.
Contact:+86-731-86303875
Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Doi:10.1007/BF00480138
()Doi:10.1021/ja01171a071
(1949)Doi:10.1007/BF01046455
(1977)Doi:10.1016/S0008-6215(00)83300-5
(1977)Doi:10.1002/hlca.19770600835
(1977)Doi:10.1016/S0022-1139(00)81521-3
(1982)
