Journal of the Chemical Society - Faraday Transactions p. 2901 - 2904 (1994)
Update date:2022-08-03
Topics:
Ichikawa, Takahisa
Ohta, Nobuaki
Shiotani, Masaru
Radiolysis of the two systems, pentane containing 3 molpercent octane, and hexane containing 3 molpercent nonane, has been investigated at 77 K in the presence of 1 molpercent alkenes.EPR studies of alk-2- and -3-ene additives show the formation of the corresponding alk-2-and -3-ene radical cations, whereas alk-1-enes with linear C-C chains are observed to give (E)-pent-2-ene radical cations in the pentane systems and (E)-hex-3-ene radical cations in the hexane systems.The effects of the alk-1-ene additives are attributed to the ion-molecule reaction, i.e. transfer of H2 from the parent n-alkane radical cations to the alk-1-ene additives to form the alkene radical cations of the parent molecules.
View MoreContact:0086-29-89196322
Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Shandong Xinhua Pharmaceutical Co.,Ltd
website:http://www.xhzy.com
Contact:+86-533-2196801
Address:1 lutai road,zhangdian dis,Zibo City
Shanghai Hongbang Medical Technology CO.,. Ltd
Contact:13671516988 /18917636693
Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.
Huangshan Violet Biological Technology Co., Ltd
Contact:+86-559-2335676
Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Doi:10.1007/BF00480138
()Doi:10.1021/ja01171a071
(1949)Doi:10.1007/BF01046455
(1977)Doi:10.1016/S0008-6215(00)83300-5
(1977)Doi:10.1002/hlca.19770600835
(1977)Doi:10.1016/S0022-1139(00)81521-3
(1982)
