Tetrahedron Letters p. 5717 - 5718 (1987)
Update date:2022-08-02
Topics:
Handa, Yuichi
Inanaga, Junji
Reduction of Cp2TiCl2 with sec-BuMgCl in THF gave a greenish deep brown solution which has been found to promote the reductive homocoupling of aromatic and α,β-unsaturated aldehydes to yield symmetrical 1,2-diols with high threo-selectivity.
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(1978)