A Facile Conversion of Alkenes to Alcohols with Benzyltriethylammonium Borohydride-Chlorotrimethylsilane

DOI: 10.1039/c39890000903

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 903 - 904 (1989)

Update date:2022-08-06

Topics:

Authors:

Baskaran, Sundarababu

Gupta, Varsha

Chidambaram, Nallaperumal

Chandrasekaran, Srinivasan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890000903

A combination of benzyltrimethylammonium borohydride and chlorotrimethylsilane (1:1) in dichloromethane at 0 deg C has been found to be a convenient reagent system for the conversion of alkenes to alcohols, the hydroxy group of which is introduced in an anti-Markovnikov manner.

Full text of DOI:10.1039/c39890000903

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(1)-exo-3,3-Dimethylbicyclo(2.2.1)heptane-2-methanol

Cas No:67560-14-9

R&D Labs maybe for 67560-14-9

jiangsu senxuan pharmaceutical and chemical co.,ltd

Contact:86-523-87982810

Address:hongqiao industrial zone,taixing,jiangsu china
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China

Relevant to this article

Synthesis of 5-aryl-3H-[1,3,4]oxadiazol-2-ones from N′-(chloro-aryl- methylene)-tert-butylcarbazates using basic alumina as an efficient and recyclable surface under solvent-free condition

Doi:10.1016/j.tetlet.2012.11.128
(2013)
Synthesis of allene ferrocenes through CuI-mediated Crabbe homologation reaction

Doi:10.1039/c2ra22806h
(2013)
Synthesis and antimicrobial activities of some newly 2,4,6-tri-substituted pyridine derivatives

Doi:10.1007/s11164-013-1028-0
(2014)
Substrate-Controlled Regioselective Iodooxygenation of Olefins

Doi:10.1055/s-0037-1609968
(2018)
Addition of thiols to o-quinone methide: New 2-hydroxy-3- phenylsulfanylmethyl[1,4]naphthoquinones and their activity against the human malaria parasite Plasmodium falciparum (3D7)

Doi:10.1016/j.ejmech.2012.10.052
(2013)
Stereoselective total synthesis of both (6R,9R,10S,7E)- and (6S,9R,10S,7E)-epimers of oxylipin (9R,10S,7E)-6,9,10-trihydroxyoctadec-7-enoic acid

Doi:10.1016/j.tet.2012.12.076
(2013)

Article Doi