Monatshefte fur Chemie p. 1421 - 1432 (1982)
Update date:2022-08-04
Topics:
Falk, Heinz
Mueller, Norbert
Ratzenhofer, Michael
Winsauer, Karl
Anaerobic irradiation of bilirubin in the region of the main absorption band produces the diastereomers of (Z,E)- and (E,Z)-configurations with high quantum yield.The structure of these "photobilirubins" is proven by a chemical correlation with the corresponding diastereomers of biliverdindimethylester characterised before.Their 1H-NMR spectroscopic features have been recorded and are discussed. - Keywords: (Z,Z)-, (Z,E)- and (E,Z)-Bilirubin; Photobilirubin; Neonatal jaundice; Phototherapy
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