β-Elimination of the Isonitrile Group in Alkylation Reactions of C-H Acids Activated by the Isonitrile Function

DOI: 10.1039/c39820000979

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 979 - 980 (1982)

Update date:2022-08-03

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Authors:

Jawdosiuk, Mikolaj

Uminski, Maciej

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Article abstract of DOI:10.1039/c39820000979

During phase-transfer alkylation of the isonitriles R1R2CHNC with X-CH2-Y, where X is a leaving group and Y an electron withdrawing group, some of the alkylation products undergo β-elimination of the isonitrile function to yield R1R2C=CHY.

Full text of DOI:10.1039/c39820000979

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