ISOMERIZATION OF tert-BUTYLDIMETHYLSILYL PROTECTING GROUPS IN RIBONUCLEOSIDES

DOI: 10.1016/S0008-6215(00)85245-3

Source and publish data:

Carbohydrate Research p. 203 - 210 (1981)

Update date:2022-08-05

Topics:

Authors:

Ogilvie, Kelvin K.

Entwistle, Douglas W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0008-6215(00)85245-3

The tert-butyldimethylsilyl group undergoes isomerization between O-2' and O-3' in ribonucleosides in solution.Isomerization is most rapid in protic solvents and extremely slow in such solvents as dry dimethyl sulfoxide, pyridine, oxolane, chloroform, or

Full text of DOI:10.1016/S0008-6215(00)85245-3

Products guided by the article

Product name:N-(9-{(2R,3R,4R,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-5-[(4-methoxy-phenyl)-diphenyl-methoxymethyl]-tetrahydro-furan-2-yl}-6-oxo-6,9-dihydro-1H-purin-2-yl)-benzamide

Cas No:70689-36-0

R&D Labs maybe for 70689-36-0

Dongguan Albiya Energy Science and Technology Co.,Ltd

Contact:+86-769-22181286

Address:Huanan Industial Park, Dongguan,China
Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China
Chengdu Push Bio-technology Co., Ltd

Contact:--

Address:No.8 Wuke West Second Road, Wuhou
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong
Tradlon Chemical Co., Ltd.

Contact:+86-710-3516804

Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei

Relevant to this article

Copper(II)-Catalyzed Tandem Decarboxylative Michael/Aldol Reactions Leading to the Formation of Functionalized Cyclohexenones

Doi:10.1021/acs.orglett.8b00607
(2018)
NaOH-promoted thiolysis of oxiranes using 2-[bis(alkylthio)methylene]-3- oxo-N-o-tolylbutanamides as odorless thiol equivalents

Doi:10.1055/s-2006-958438
(2007)
Doi:10.1055/s-1979-28675
(1979)
Dynamic NMR study of the tautomerism of bicyclic oxalamidines: Kinetic HH/HD/DD isotope and solvent effects

Doi:10.1021/ja00083a009
(1994)
Short and efficient process for the synthesis of trans-4- aminocyclohexanecarboxylic acid derivatives

Doi:10.1021/op900195w
(2009)
Ureidobenzotriazine multiple H-bonding arrays: The importance of geometrical details on the stability of H-bonds

Doi:10.1021/jo7019338
(2008)

Article Doi