ISOMERIZATION OF tert-BUTYLDIMETHYLSILYL PROTECTING GROUPS IN RIBONUCLEOSIDES

DOI: 10.1016/S0008-6215(00)85245-3

Source and publish data:

Carbohydrate Research p. 203 - 210 (1981)

Update date:2022-08-05

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Authors:

Ogilvie, Kelvin K.

Entwistle, Douglas W.

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Article abstract of DOI:10.1016/S0008-6215(00)85245-3

The tert-butyldimethylsilyl group undergoes isomerization between O-2' and O-3' in ribonucleosides in solution.Isomerization is most rapid in protic solvents and extremely slow in such solvents as dry dimethyl sulfoxide, pyridine, oxolane, chloroform, or

Full text of DOI:10.1016/S0008-6215(00)85245-3

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