Journal of Organic Chemistry p. 3412 - 3421 (1982)
Update date:2022-08-05
Topics: Decomposition Chromatography Photolysis Spectroscopy Quantum Yield Excitation
Fox, Marye Anne
Singletary, Nancy J.
Visible or long-wavelength ultraviolet excitation of alkali metal salts of cyclooctadiene leads to electron exchange.Primary photoinduced electron transfer has been used to initiate the geometrical isomerization of cis-stilbene and the photosubstitution of aryl halides.Mechanistic details for these reactions are presented.Electron exchange so dominates the excited-state reactivity of this pentadienyl anion that neither potential pericyclic reaction (i.e., electrocyclization or sigmatropic shifts) nor photoinduced cis-trans isomerization can be detected.
View MoreContact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
website:http://www.ringchemicals.com/
Contact:+1-416-493-6870
Address:Toronto, Canada
Contact:+33-5-34012600
Address:28 ZA des Pignès
website:http://www.ringchemicals.com/
Contact:+1-416-493-6870
Address:Toronto, Canada
website:https://www.sinoshiny.com/products
Contact:+86-20-62802632;62802633
Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Doi:10.1021/jo01290a009
(1980)Doi:10.1021/jm00151a021
(1986)Doi:10.3390/molecules25092128
(2020)Doi:10.1021/ja056649r
(2006)Doi:10.1016/S0040-4039(01)80849-2
(1985)Doi:10.1021/ja00262a024
(1986)
