Heterocyclic Cation Systems. 14. Synthesis of Thienodiazepine, Thiazolodiazepine, and s-Triazolothiazolodiazepine Derivatives

DOI: 10.1021/jo01290a010

Source and publish data:

Journal of Organic Chemistry p. 253 - 260 (1980)

Update date:2022-08-04

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Authors:

Hirai, Kentaro

Sugimoto, Hirohiko

Ishiba, Teruyuki

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Article abstract of DOI:10.1021/jo01290a010

Synthesis of hetero<1,4>diazepines is described.The synthetic route involved reactions of the anion of malononitrile or cyanamide toward 2-substituted 1,3-oxathiolium cation 1 to give amino ketone derivatives 3 and 4 as the key intermediates.Introducti

Full text of DOI:10.1021/jo01290a010

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