Journal of the American Chemical Society p. 1722 - 1732 (1990)
Update date:2022-08-05
Topics: Steric hindrance Isomerization Electronic effects Concerted Mechanism Kinetic Control Thermodynamic Control Cope Rearrangement Diene Phenyl group Pericyclic reaction Transition state Sigmatropic rearrangement Bicyclic compound Bicyclo[3
Roth, Wolfgang R.
Lennartz, Hans-Werner
Doering
Birladeanu, Ludmila
Guyton, Catherine A.
Kitagawa, Toshikazu
The title reaction constitutes a reliable model of a nonconcerted, diradical mechanism closely related to a Cope rearrangement. Its activation parameters relate to a transition state approximated by 1,5-diphenylcyclohepta-1,5-diyl (7). Force field calcula
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