Synthesis of Chartreusin Aglycone

DOI: 10.1021/ja00522a059

Source and publish data:

Journal of the American Chemical Society p. 798 - 799 (1980)

Update date:2022-08-04

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Authors:

Kelly, T. Ross

Magee, Joseph A.

Weibel, Franz R.

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Article abstract of DOI:10.1021/ja00522a059

A short regiospecific synthesis of chartreusin aglycone (2) is described.Diels-Alder addition of 4 and 5 under oxidizing conditions affords benzanthracenedione 6.Reductive methylation of 6 gives 7 (90percent), which is oxidatively cleaved to diacid 8 (54p

Full text of DOI:10.1021/ja00522a059

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