
Tetrahedron Letters p. 1017 - 1020 (1980)
Update date:2022-09-26
Topics:
Koenigkramer, Rusty E.
Zimmer, Hans
Diethyl 1-phenyl-1-trimethylsiloxymethane phosphonate carbanion was found to react as an effective acyl anion equivalent in the preparation of α-hydroxy ketones from aliphatic and aromatic aldehydes and ketones.A 1,4-oxygen-oxygen silicon migration was also observed.
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