α-HETEROSUBSTITUTED PHOSPHONATE CARBANIONS IX : DIETHYL 1-PHENYL-1-TRIMETHYLSILOXYMETHANE PHOSPHONATE AS AN ACYL ANION EQUIVALENT; A NOVEL METHOD FOR THE PREPARATION OF α-HYDROXYKETONES.

DOI: 10.1016/S0040-4039(00)78827-7

Source and publish data:

Tetrahedron Letters p. 1017 - 1020 (1980)

Update date:2022-09-26

Topics:

Authors:

Koenigkramer, Rusty E.

Zimmer, Hans

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Article abstract of DOI:10.1016/S0040-4039(00)78827-7

Diethyl 1-phenyl-1-trimethylsiloxymethane phosphonate carbanion was found to react as an effective acyl anion equivalent in the preparation of α-hydroxy ketones from aliphatic and aromatic aldehydes and ketones.A 1,4-oxygen-oxygen silicon migration was also observed.

Full text of DOI:10.1016/S0040-4039(00)78827-7

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