α-HETEROSUBSTITUTED PHOSPHONATE CARBANIONS IX : DIETHYL 1-PHENYL-1-TRIMETHYLSILOXYMETHANE PHOSPHONATE AS AN ACYL ANION EQUIVALENT; A NOVEL METHOD FOR THE PREPARATION OF α-HYDROXYKETONES.

DOI: 10.1016/S0040-4039(00)78827-7

Source and publish data:

Tetrahedron Letters p. 1017 - 1020 (1980)

Update date:2022-09-26

Topics:

Authors:

Koenigkramer, Rusty E.

Zimmer, Hans

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78827-7

Diethyl 1-phenyl-1-trimethylsiloxymethane phosphonate carbanion was found to react as an effective acyl anion equivalent in the preparation of α-hydroxy ketones from aliphatic and aromatic aldehydes and ketones.A 1,4-oxygen-oxygen silicon migration was also observed.

Full text of DOI:10.1016/S0040-4039(00)78827-7

Products guided by the article

Product name:Diethyl 2-(4-cyanophenyl)-2-hydroxy-1-(trimethylsiloxy)-1-phenylethanephosphonate

Cas No:74562-17-7

R&D Labs maybe for 74562-17-7

N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Chen jie

Contact:027-87677569

Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Allicon Pharmaceuticals,Inc.

Contact:+86-519-86339586，13584329896

Address:Changzhou Scientific and Education Park
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China

Relevant to this article

Eudesmane-type sesquiterpene derivatives from Saussurea conica

Doi:10.1002/hlca.200490131
(2004)
Selective electrocatalysis of alkenes in aqueous media. A comparison of reactivities for oxoferryl porphyrin and oxoferryl porphyrin radical cation at room temperature

Doi:10.1039/cc9960001437
(1996)
Preparation of triazolobenzodiazepine derivatives as Vasopressin V1a antagonists

Doi:10.1016/j.tetlet.2011.08.011
(2011)
Doi:10.1021/ja01871a008
(1939)
The First Practical Method for Asymmetric Epoxidation

Doi:10.1021/ja00538a077
(1980)
Diastereoselective synthesis of 10b-substituted hexahydropyrroloisoquinolines from L-tartaric acid. Creation of a quaternary carbon stereocentre via N-acyliminium ion cyclization

Doi:10.1016/j.tetlet.2004.06.036
(2004)

Article Doi