Journal of the Chemical Society. Chemical communications p. 185 - 186 (1980)
Update date:2022-08-04
Topics:
Bateson, John H.
Roberts, Patricia M.
Smale, Terence C.
Southgate, Robert
Base-catalysed addition of thiols to 7-oxo-1-azabicyclo<3.2.0>hept-2-ene-2-carboxylates produces adducts of the saturated nucleus, which can be stereospecifically oxidised to α-chlorosulfoxides and then dehydrochlorinated to form antibacterially active sulfoxides of the corresponding unsaturated system.
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