Tetrahedron p. 1299 - 1306 (1985)
Update date:2022-07-30
Topics:
Bellassoued, M.
Habbachi, F.
Gaudemar, M.
The condensation of aldehydes and ketones with the bromozinc salt derived from γ-bromocrotonic acid, in the presence of zinc, yield to the "linear" and "branched" unsaturated hydroxyacids.These latters, which represent the kinetic products of the reaction, equilibrate at the alcoholate state to give, after hydrolysis, the "linear" compounds.
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Doi:10.3987/COM-92-S(T)102
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