NITROXYDES 94: DECOMPOSITION THERMIQUE D'UN RADICAL OXAZOLIDINE-OXYLE.

DOI: 10.1016/S0040-4039(00)93654-2

Source and publish data:

Tetrahedron Letters p. 1949 - 1952 (1980)

Update date:2022-07-30

Topics:

Authors:

Michon, Josette

Rassat, Andre

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Article abstract of DOI:10.1016/S0040-4039(00)93654-2

Pyrolysis of spiro<(4-t-butyl cyclohexane)-1,2'-(4',4'-dimethyl oxazolidine-3' oxyl)> 1 leads to spiro<(4-t-butyl cyclohexane)-1,2'-(4',4' oxazolidine 3'-hydroxy)> 2, 4-t-butyl cyclohexanone and 4-t-butyl cyclohexanoxime.Kinetic studies show that the reaction proceeds through an autocatalytic process.

Full text of DOI:10.1016/S0040-4039(00)93654-2

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