Journal of the American Chemical Society p. 5602 - 5605 (1980)
Update date:2022-08-02
Topics:
Rebek, J.
McCready, R.
A number of α-substituted hydroperoxides were examined for their ability to epoxidize olefins in a stereospecific manner.Hydroperoxy ethers, amines, carbonyl compounds, and nitriles showed this capability.Intramolecular epoxidation was demonstrated in cases where ortho esters of some olefinic alcohols were treated with H2O2, and methyl orthooleate - H2O2 mixtures also epoxidized the internal olefin in an intramolecular reaction.Attempts to generate chiral hydroperoxides for asymmetric epoxidation are described and structural features required for epoxidation reagents are discussed.
View MoreBeijing Top Science biological technology co., LTD
Contact:+86-13439059536
Address:15-1705 jre three mile, Beijing 100000,CHINA
Jiangsu Cale New Material Co.ltd
Contact:+86-515-88334667/88203550
Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Zhejiang Haizhou Pharmaceutical Co., Ltd.
website:https://www.haizhoupharma.com/
Contact:+86-576-88221016
Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
Changsha Huajing Powdery Material Technological Co., Ltd.
Contact:86-731-88879686
Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Sanming Coffer Fine Chemical Industrial Co., Ltd
website:http://www.cofferxm.com/
Contact:+86-598-5853979
Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
Doi:10.1016/S0022-1139(99)00238-9
(2000)Doi:10.1016/S0008-6215(00)85376-8
(1980)Doi:10.1248/cpb.28.1043
(1980)Doi:10.2478/s11696-010-0020-z
(2010)Doi:10.1021/jo01092a039
(1959)Doi:10.1016/j.tetlet.2004.10.077
(2004)
