THE ARBUZOV REACTION OF TRIETHYL PHOSPHITE WITH ELEMENTAL IODINE

DOI: 10.1016/S0040-4039(00)71202-0

Source and publish data:

Tetrahedron Letters p. 321 - 322 (1980)

Update date:2022-07-29

Topics:

Authors:

Skowronska, S.

Pakulkski, M.

Michalski, J.

Cooper, D.

Trippett, S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)71202-0

Triethyl phosphite and elemental iodine in solution give transient iodotriethylphosphonium iodine which eliminates ethyl iodine to form diethyl phosphoroiodidate.An examination of the 31P NMR and IR spectra over the temperature range -100 deg C -0 deg C fails to disclose any evidence for triethoxydi-iodophosphorane, contrary to a previous claim.

Full text of DOI:10.1016/S0040-4039(00)71202-0

Products guided by the article

Product name:diethyl phosphoroiodidate

Cas No:74745-85-0

R&D Labs maybe for 74745-85-0

Chiral Quest (Suzhou) Company Ltd

website:http://www.chiralquest.com

Contact:+86-0512-62956066

Address:B1/9, 218 Xinghu Street, Suzhou Industrial Park
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Aqua Chem Industry Co., Ltd

Contact:+86-515-88356562

Address:No.2, West Daqing Road, Yancheng, Jiangsu, China
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China

Relevant to this article

Copper-catalyzed one-pot synthesis of unsymmetrical arylurea derivatives via tandem reaction of diaryliodonium salts with N -arylcyanamide

Doi:10.1021/jo501334u
(2014)
Unique Properties of Chromophore-Containing Bilayer Aggregates: Enhanced Chirality and Photochemically Induced Morphological Change

Doi:10.1021/ja00541a081
(1980)
Doi:10.1246/bcsj.52.3763
(1979)
Physical Binding of Tetraols Derived from 7,8-Dihydroxy-9,10-epoxybenzo pyrene to DNA

Doi:10.1021/ja00537a043
(1980)
Effect (or lack thereof) of ancillary groups on the preparation and spectroscopic properties of ruthenium silyl complexes containing the Cp(PR₃)₂Ru moiety

Doi:10.1021/om0204235
(2002)
On the metabolites of penicillium duclauxi delacroix--3. The reactions of duclauxin with ammonia and primary amines. The structures of desacetylduclauxin, neoclauxin, xenoclauxin and cryptoclauxin.

Doi:10.1016/S0040-4039(01)99876-4
(1966)

Article Doi