THE ARBUZOV REACTION OF TRIETHYL PHOSPHITE WITH ELEMENTAL IODINE

DOI: 10.1016/S0040-4039(00)71202-0

Source and publish data:

Tetrahedron Letters p. 321 - 322 (1980)

Update date:2022-07-29

Topics:

Authors:

Skowronska, S.

Pakulkski, M.

Michalski, J.

Cooper, D.

Trippett, S.

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Article abstract of DOI:10.1016/S0040-4039(00)71202-0

Triethyl phosphite and elemental iodine in solution give transient iodotriethylphosphonium iodine which eliminates ethyl iodine to form diethyl phosphoroiodidate.An examination of the 31P NMR and IR spectra over the temperature range -100 deg C -0 deg C fails to disclose any evidence for triethoxydi-iodophosphorane, contrary to a previous claim.

Full text of DOI:10.1016/S0040-4039(00)71202-0

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