Organocuprate-Induded Coupling of Propargyl or Enyne Alcohols Using (Methylphenylamino)tributylphosphonium Iodide. Regiocontrolled Synthesis of Allenes and Conjugated Enynes

DOI: 10.1021/jo01310a066

Source and publish data:

Journal of Organic Chemistry p. 4536 - 4538 (1980)

Update date:2022-08-05

Topics:

Authors:

Tanigawa, Yoshio

Murahashi, Shun-Ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01310a066

Regioselective synthesis of allenes is directly achieved via organocuprate-mediated γ-coupling of propargyl alcohols by using the title reagent (1). Alternatively, the coupling between 1,4-enyn-3-ols and alkyllithium affords the conjugated Z enynes regio-

Full text of DOI:10.1021/jo01310a066

Products guided by the article

Product name:(1,3-Dimethyl-hepta-1,2-dienyl)-benzene

Cas No:75031-50-4

R&D Labs maybe for 75031-50-4

Weifang Jahwa Chemical Co.,Ltd

Contact:0086-536-8897731,8897730

Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
shijiazhuang baisheng chem co.; ltd

Contact:86-0311-80790826

Address:shijiazhuang hebei
Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County

Relevant to this article

REACTION OF ACYL ISOCYANATES WITH β-KETO ESTERS

Doi:10.1007/BF00958817
(1980)
PREPARATION, REACTIONS AND CATALYTIC ACTIVITY OF COMPLEXES OF THE TYPE 2>A (R = Cl, F, H, CH3, OR CH3O; A = ClO4^- OR B(C6H5)4^-)

Doi:10.1016/S0022-328X(00)86083-0
(1980)
Metabolic β-hydroxylation and N-oxidation of N'-nitrosonornicotine

Doi:10.1021/jm00185a005
(1980)
The Structure of the 1-Thyminylacetic Acid and Tyramine (1:1) Complex

Doi:10.1107/S056774088000800X
(1980)
Isolation of Diazacycloheptatetraenes from Thermal Nitrene-Nitrene Rearrangements

Doi:10.1021/ja00539a039
(1980)
2,7-Diazabicyclo[2.2.1]heptanes: Novel asymmetric access and controlled bridge-opening

Doi:10.1039/c8cc10263e
(2019)

Article Doi