Synthesis of the Food Mutagens MeIQx and 4,8-DiMeIQx by Copper(I) Promoted Quinoxaline Formation

DOI: 10.1016/0040-4020(89)80127-9

Source and publish data:

Tetrahedron p. 1293 - 1298 (1989)

Update date:2022-08-05

Topics:

Authors:

Knapp, Spencer

Ziv, Joseph

Rosen, Joseph D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(89)80127-9

The regiocontrolled syntheses of the title compounds (1 and 2) is described.The key step is a new intramolecular alkyne amination and aromatization process (5 <*> 6; 8 <*> 9) effected by tetrakis(acetonitrile)copper(I) tetrafluoroborate.

Full text of DOI:10.1016/0040-4020(89)80127-9

Products guided by the article

Product name:2,4-dinitro-N-(prop-2-ynyl)aniline

Cas No:75077-45-1

R&D Labs maybe for 75077-45-1

LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Kaymossy BioChem Tech Co., Ltd

website:http://www.kaimosi.com

Contact:0571-87191913/0571-87199097

Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China
suzhou BetterBioChem Co., Ltd.

website:http://www.betterbiochem.com

Contact:+86-18013506594

Address:No. 8 Building, 18 nong, Xi Yingnan Road, Pudong, Shanghai,China
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China

Relevant to this article

On the Reactivity of Thiomorpholine and Alkyl Substituted Thiomorpholines 4. (On the Joint Action of Elementary Sulfur and Gaseous Ammonia on Ketones, 94.)

Doi:10.1007/BF00903234
(1980)
THE REACTIONS OF (L = R3P OR RNC) WITH CARBON DISULPHIDE AND ORGANOISOTHIOCYANATES

Doi:10.1016/S0022-328X(00)90639-9
(1980)
Electronic Control of Stereoselectivity. 6. Directionality of Singlet Oxygen Addition to 1,4-Dimethoxynaphthalenes Laterally Fused to Bridged Bicyclic Systems

Doi:10.1021/jo01312a019
(1980)
Doi:10.1021/jo01345a026
(1966)
Novel amino propyl substituted organo tin compounds

Doi:10.1139/cjc-2013-0504
(2014)
Synthesis of 3-substituted dihydro-1-phenylamino-1h-pyrrolo[1,2-a] imidazole-2,5(3h,6h)-diones from α-amino acid phenylhydrazides and levulinic acid

Doi:10.1002/ejoc.200400112
(2004)

Article Doi