Synthesis of the Food Mutagens MeIQx and 4,8-DiMeIQx by Copper(I) Promoted Quinoxaline Formation

DOI: 10.1016/0040-4020(89)80127-9

Source and publish data:

Tetrahedron p. 1293 - 1298 (1989)

Update date:2022-08-05

Topics:

Authors:

Knapp, Spencer

Ziv, Joseph

Rosen, Joseph D.

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Article abstract of DOI:10.1016/0040-4020(89)80127-9

The regiocontrolled syntheses of the title compounds (1 and 2) is described.The key step is a new intramolecular alkyne amination and aromatization process (5 <*> 6; 8 <*> 9) effected by tetrakis(acetonitrile)copper(I) tetrafluoroborate.

Full text of DOI:10.1016/0040-4020(89)80127-9

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