Michaelis-Arbuzow Intermediates: X-Ray Crystal Structures of the Methyl Bromide Adducts of Neopentyl Diphenylphosphinite and Dineopentyl Phenylphosphonite

DOI: 10.1039/C39800000226

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 226 - 227 (1980)

Update date:2022-07-30

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Authors:

Hendrick, Kim

Hudson, Harry R.

Kow, Aloysius

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Article abstract of DOI:10.1039/C39800000226

Single crystal X-ray structure determinations of the Michaelis-Arbuzov intermediates Ph2Me(Bu^tCH2O)P⁺Br^- and PhMe(Bu^tCH2O)2P⁺Br^- clearly demonstrate that these species are four-co-ordinate phosphonium salts.

Full text of DOI:10.1039/C39800000226

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