Tetrahedron Letters p. 2487 - 2490 (1980)
Update date:2022-08-04
Topics:
Hudlicky
Koszyk
The thermolytic behavior of 6β-ethenyl-1β-methyl-bicyclo [3.1.0] hexane-2-one was examined at a wide range of temperatures and with diverse catalytic surfaces. Conditions are reported to effect selectivity between the retro-ene and the cyclopentene modes of rearrangement. The synthetic scope of these transformations is indicated.
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Doi:10.1002/anie.201703610
(2017)Doi:10.1021/ja01098a512
(1953)Doi:10.1021/ja01629a061
(1955)Doi:10.1246/bcsj.53.1670
(1980)Doi:10.1134/S1070428006040129
(2006)Doi:10.1055/s-0035-1562541
(2016)
