Tetrahedron Letters p. 1559 - 1562 (1980)
Update date:2022-08-03
Topics:
Kocienski, Philiph J.
α-Phenylthioalkyltrimethylsilanes, readily prepared by the alkylation of phenylthiomethyltrimethylsilane with alkyl halides or epoxides, can be converted to O-trimethylsilyl hemithioacetals via a Sila-Pummerer Rearrangement of the corresponding sulfoxides.The O-trimethylsilyl hemithioacetals are readily hydrolyzed to aldehydes.
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Doi:10.1039/d1sc01741a
(2021)Doi:10.1016/S0040-4039(00)78636-9
(1980)Doi:10.1016/0040-4039(80)80026-8
(1980)Doi:10.1021/ol049187f
(2004)Doi:10.1016/j.steroids.2005.06.003
(2005)Doi:10.1002/hlca.19800630411
(1980)
