Journal of the Chemical Society, Dalton Transactions p. 1434 - 1438 (1980)
Update date:2022-08-05
Topics:
Anderson, Gordon K.
Cross, Ronald J.
Phosphorus-31 n.m.r. studies of the reaction of trans-a metastable five-co-ordinate compound in non-polar solvents, which eliminates a halide to form ionic species trans-a benzoyl complex.A direct carbonyl insertion route from a five-co-ordinate intermediate also operates, independently of the phosphine elimination pathways, and this becomes the predominant pathways with more nucleophilic PR3 ligands.The use of elemental sulphur to remove PR3 from the reaction mixtures was instrumental in identifying some intermediates, and this method has potential synthetic value in replacing PR3 by weaker ligands at platinum.
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Doi:10.1002/ardp.19803130615
(1980)Doi:10.1021/jm049904b
(2004)Doi:10.1021/ja00547a004
(1980)Doi:10.1016/S0040-4020(96)01118-0
(1997)Doi:10.1021/bi00859a039
(1967)Doi:10.1021/jo01314a062
(1980)
