Journal of Organic Chemistry p. 5430 - 5432 (1980)
Update date:2022-08-05
Topics:
Vettel, Paula Roach
Coates, Robert M.
An 18-step total synthesis of the novel zizaane sesquiterpenes, (-)-prezizaene (1) and (-)-prezizanol (2), from (+)-pulegone is described; the key step of the synthesis is the intramolecular ring expansion of (diazoethyl)hydrindanone 12 to the isomeric me
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