One-pot preparation of aroylsilanes by reductive silylation of methyl benzoates

Article abstract of DOI:10.1080/00397919708006819

A one-pot synthesis of aroylsilanes based on reductive silylation of methyl benzoates using Mg/I2/chlorosilane in nontoxic 1-methyl-2- pyrrolidinone (NMP) solvent, is described. The yields are moderate to good and the method has been used for the preparation of some new bifunctional aroylsilanes.

Full text of DOI:10.1080/00397919708006819

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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One-Pot Preparation of
Aroylsilanes by Reductive
Silylation of Methyl Benzoates
Emily C. Tongco a , Qunjie Wang a & G. K. Surya
Prakash a
a Donald P. and Katharine B. Loker Hydrocarbon
Research Institute and, Department of Chemistry ,
University of Southern Caifornia, University Park,
Los Angeles, CA, 90089-1661
Published online: 22 Aug 2006.
To cite this article: Emily C. Tongco , Qunjie Wang & G. K. Surya Prakash (1997) One-
Pot Preparation of Aroylsilanes by Reductive Silylation of Methyl Benzoates, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 27:12, 2117-2123, DOI: 10.1080/00397919708006819
To link to this article: http://dx.doi.org/10.1080/00397919708006819
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