Journal of Organic Chemistry p. 614 - 619 (1981)
Update date:2022-08-02
Topics:
Ohashi, Shinichi
Ruch, Wayne E.
Butler, George B.
The reaction between allyltrimethylsilane (1) and 4-phenyl-1,2,4-triazoline-3,5-dione (2) was studied, and the structures of three products were determined by using 1H NMR, 13C NMR, and mass spectra.The effects of solvent and temperature on the relative yields of products were studied, and a reaction mechanism involving an ionic intermediate was suggested.The mechanism of the reaction between diallyldimethylsilane (3) with triazolinediones was found to be quite similar to that of 1.
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