Tetrahedron p. 1817 - 1820 (1980)
Update date:2022-09-26
Topics:
Mishnev, A. F.
Bleidelis, J. J.
Venters, K. K.
X-ray crystallography established the structure of the acetyl nitrate adduct to furfural diacetate (H.Gilman and G.F.Wright (1930)) as trans-2-acetoxy-5-nitro-2,5-dihydro-2-furfural diacetate (1a).The furanoid ring is essentially planar, its geometry being similar to that of 2,5-dihydrofuran molecule, except for the interatomic distance C(3)-C(4) which is shorter than the corresponding length of double C-C bond in alkenes.The C(5)-N 1.52 Angstroem bond significantly exceeds the standard C-N bond lengths in nitroalkanes and nitrobenzene.
View MoreNanjing Chemipioneer Pharma&Tech Co.,Ltd
website:http://www.chemipioneer.com.cn
Contact:+86-25-52685700
Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China
Daicel Chiral Technologies (China)CO.,LTD
Contact:021-5046-0086*8
Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Contact:+86 18616952870
Address:Area
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Shanghai Harvest Chemical Ind. Co., Ltd.
Contact:021-51385350
Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
Doi:10.1021/jo00319a027
(1981)Doi:10.1021/jo00085a036
(1994)Doi:10.1016/S0008-6215(00)84562-0
(1980)Doi:10.1016/S0040-4039(00)84488-3
(1986)Doi:10.1039/b406280a
(2004)Doi:10.1016/j.bmc.2007.01.044
(2007)
