Journal of Organometallic Chemistry p. 105 - 112 (1980)
Update date:2022-08-05
Topics:
Piotrowski, A.
Kunicki, A.
Pasynkiewicz, S.
The reactions of benzonitrile with tetraethylaluminoxane and with tetraethylaluminoxane in 1:1 molar ratio were studied.In the case of tetraethylaluminoxane 1,3,5-triphenyl-2,4-diaza-1-aminoheptadiene-1,4, Ph(Et)HCN=C(Ph)N=C(Ph)NH2, was found to be the main product after hydrolysis, 1,3-diphenyl-2-aza-1-aminopentene-1, Ph(Et)HCN=C(Ph)NH2, 2,4,6-triphenylazine-1,3,5; 5-methyl-2,4,6-triphenylpyrimidine, propiophenone and benzaldehyde were also formed.A reaction scheme is proposed.In the case of Me4AL2O, acetophenone was formed as the main product after hydrolysis.
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(1980)
