
Monatshefte fur Chemie p. 1015 - 1024 (1980)
Update date:2022-08-04
Topics:
Hammerschmidt, Friedrich
Zbiral, Erich
Acylphosphonates 1 react with Sulfur-ylides 2 to give enolphosphates 3 and phosphonophosphates 4.The product ratio of 3 and 4 is determined by the substituent R3.If R3 is not electronwithdrawing the phosphonophosphate 4 is the sole reaction product. - Keywords: Acylphosphonates, behaviour towards S-ylides; Rearrangement of α-hydroxyphosphonates
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