Journal of the Chemical Society. Perkin transactions I p. 270 - 277 (1981)
Update date:2022-08-04
Topics:
Annis, Gary D.
Ley, Steven V.
Self, Christopher R.
Sivaramakrishnan, Ramamoorthy
A number of tricarbonyliron-lactone complexes have been prepared from vinyl oxirans by treatment with pentacarbonyliron.In certain cases two ν3-allyl complexes were isolated from a single vinyl oxiran.Oxidation of the complexes by cerium (IV) ammonium nitrate in acetonitrile leads predominantly to β-lactones.The stereochemical integrity of the initial complexes is reflected in the formation of the oxidation products.Reduction of these products with lithium aluminium hydride gave the expected diols.
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Doi:10.1055/s-1981-29357
(1981)Doi:10.1016/0040-4039(80)80149-3
(1980)Doi:10.1021/ol026961v
(2003)Doi:10.1021/jo049351c
(2004)Doi:10.1021/jo00328a035
(1981)Doi:10.1016/0040-4020(80)88046-X
(1980)
