PENTADIENYLSILANES AS NEW REAGENTS OF THE SITESELECTIVE DIENYLMETHYLATION OF ELECTROPHILES PROMOTED BY A LEWIS ACID

DOI: 10.1016/0040-4039(80)80177-8

Source and publish data:

Tetrahedron Letters p. 3783 - 3786 (1980)

Update date:2022-08-02

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Authors:

Hosomi, Akira

Saito, Masaki

Sakurai, Hideki

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Article abstract of DOI:10.1016/0040-4039(80)80177-8

(2,4-Pentadienyl)- and (2,4-hexadienyl)trimethylsilanes, prepared from the corresponding pentadienylpotassiums and trimethylchlorosilane, react smoothly with various electrophiles such as acetals, aldehydes and acid halides to give pentadienylation produc

Full text of DOI:10.1016/0040-4039(80)80177-8

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