Journal of the Chemical Society. Perkin transactions I p. 403 - 407 (1981)
Update date:2022-08-04
Topics:
Mendoza, Javier de
Millan, Carles
Rull, Pedro
A synthesis of a 1,1'-bibenzimidazole (2; R = Me), through two successive heterocyclizations on 2,2'-azoaniline, is reported.Alternative routes to (2) by direct formation of the N-N bond from the appropriate N-substituted-benzimidazoles were unsuccessful.The dimer (2) shows great thermal and photochemical stability towards hydrogen abstraction and addition to olefins.Although the N-N bond can be easily cleaved by irradiation in ethanol, all attempts to detect the neutral radical benzimidazol-1-yl (1; R = Me) from (2) have been unsuccessful.Hydrogen abstraction by (1) is, however, observed with 1-iodobenzimidazole as the precursor.
View MoreChengdu Shengnuo Biological Technology Co., Ltd.
Contact:86-028-85275045
Address:Sichuan Province Chengdu hi tech Zone Tianfu Avenue North of 1480
Shanggao Ruiya Fine Chemicals Co., Ltd
Contact:+86-795-2592103
Address:Xingguang Nanlu,Shanggao County Industry Park
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)
Contact:+86-571-87046953
Address:No. 37, Qingchun Road
Contact:+86-22-26358246
Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
website:http://www.arromax.com
Contact:+86-0512-62959601 skype:aimmezhang
Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Doi:10.1016/j.tetlet.2007.04.084
(2007)Doi:10.1016/S0022-328X(00)84584-2
(1981)Doi:10.1016/S0040-4020(01)85702-1
(1994)Doi:10.1002/jhet.5570410413
(2004)Doi:10.1021/ja00400a043
(1981)Doi:10.1016/S0040-4039(01)90102-9
(1984)
